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甲苯安全技术说明书MSDS英文版

发布日期: 2024-05-14 作者: 超级管理员 点击:37 数字:{content:zishu operate=/3 decimal=1}

SAFETY DATA SHEETS

According to the UN GHS revision 9

Version: 1.0

Creation Date: July 15, 2023

Revision Date: July 15, 2023

SECTION 1: Identification

1.1GHS Product identifier

Product name

Toluene

1.2Other means of identification

Product number

-

Other names

methylbenzol; Benzene, methyl-; Toluene

1.3Recommended use of the chemical and restrictions on use

Identified uses


Uses advised against


1.4Supplier's details

Company

Kun shan minglong

Address


Telephone


1.5Emergency phone number

Emergency phone number

13914990770

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification

2.1Classification of the substance or mixture

Flammable liquids, Category 2

Skin irritation, Category 2

Aspiration hazard, Category 1

Specific target organ toxicity – single exposure, Category 3

Specific target organ toxicity – repeated exposure, Category 2

Reproductive toxicity, Category 2

2.2GHS label elements, including precautionary statements

Pictogram(s)  
Signal word

Danger

Hazard statement(s)

H225 Highly flammable liquid and vapour

H315 Causes skin irritation

H304 May be fatal if swallowed and enters airways

H336 May cause drowsiness or dizziness

H373 May cause damage to organs through prolonged or repeated exposure

Precautionary statement(s)
Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P264 Wash ... thoroughly after handling.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P203 Obtain, read and follow all safety instructions before use.

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P321 Specific treatment (see ... on this label).

P332+P317 If skin irritation occurs: Get medical help.

P362+P364 Take off contaminated clothing and wash it before reuse.

P301+P316 IF SWALLOWED: Get emergency medical help immediately.

P331 Do NOT induce vomiting.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P319 Get medical help if you feel unwell.

P318 IF exposed or concerned, get medical advice.

Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

2.3Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1Substances

Chemical nameCommon names and synonymsCAS numberEC numberConcentration
TolueneToluene108-88-3203-625-9100%

SECTION 4: First-aid measures

4.1Description of necessary first-aid measures

If inhaled

Fresh air, rest. Refer for medical attention.

Following skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

4.2Most important symptoms/effects, acute and delayed

no data available

4.3Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures

5.1Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

5.2Specific hazards arising from the chemical

Highly flammable. Vapour/air mixtures are explosive.

5.3Special protective actions for fire-fighters

Use powder, AFFF, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

SECTION 6: Accidental release measures

6.1Personal precautions, protective equipment and emergency procedures

Evacuate danger area! Consult an expert! Personal protection: chemical protection suit and self-contained breathing apparatus. Ventilation. Remove all ignition sources. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.2Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1Precautions for safe handling

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2Conditions for safe storage, including any incompatibilities

Fireproof. Separated from strong oxidants.

SECTION 8: Exposure controls/personal protection

8.1Control parameters

Occupational Exposure limit values

TLV: 20 ppm as TWA; A4 (not classifiable as a human carcinogen); BEI issued.MAK: 190 mg/m3, 50 ppm; peak limitation category: II(4); skin absorption (H); pregnancy risk group: C.EU-OEL: 192 mg/m3, 50 ppm as TWA; 384 mg/m3, 100 ppm as STEL; (skin)

Biological limit values

no data available

8.2Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety goggles.

Skin protection

Protective gloves.

Respiratory protection

Use ventilation, local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Colorless liquid

Colour

no data available

Odour

no data available

Melting point/freezing point

-95 °C

Boiling point or initial boiling point and boiling range

110-111°C(lit.)

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

4°C

Auto-ignition temperature

997°F

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

In water: 0.5 g/L (20 °C)

Partition coefficient n-octanol/water

2.69

Vapour pressure

22 mm Hg ( 20 °C)

Density and/or relative density

0.865g/mLat 25°C(lit.)

Relative vapour density

3.2 (vs air)

Particle characteristics

no data available

SECTION 10: Stability and reactivity

10.1Reactivity

no data available

10.2Chemical stability

no data available

10.3Possibility of hazardous reactions

The vapour mixes well with air, explosive mixtures are easily formed. As a result of flow, agitation, etc., electrostatic charges can be generated.Reacts violently with strong oxidants. This generates fire and explosion hazard.

10.4Conditions to avoid

no data available

10.5Incompatible materials

no data available

10.6Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available

  • Inhalation: no data available

  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

The substance is irritating to the eyes and respiratory tract. The substance may cause effects on the central nervous system. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Exposure at high levels could cause cardiac dysrhythmia and unconsciousness.

STOT-repeated exposure

The substance defats the skin, which may cause dryness or cracking. The substance may have effects on the central nervous system. Exposure to the substance may increase noise-induced hearing loss. Animal tests show that this substance possibly causes toxicity to human reproduction or development.

Aspiration hazard

A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

SECTION 12: Ecological information

12.1Toxicity

  • Toxicity to fish: no data available

  • Toxicity to daphnia and other aquatic invertebrates: no data available

  • Toxicity to algae: no data available

  • Toxicity to microorganisms: no data available

12.2Persistence and degradability

no data available

12.3Bioaccumulative potential

no data available

12.4Mobility in soil

no data available

12.5Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1UN Number

ADR/RID: UN1294 (For reference only, please check.)IMDG: UN1294 (For reference only, please check.)IATA: UN1294 (For reference only, please check.)

14.2UN Proper Shipping Name

ADR/RID: TOLUENE (For reference only, please check.)IMDG: TOLUENE (For reference only, please check.)IATA: TOLUENE (For reference only, please check.)

14.3Transport hazard class(es)

ADR/RID: 3 (For reference only, please check.)IMDG: 3 (For reference only, please check.)IATA: 3 (For reference only, please check.)

14.4Packing group, if applicable

ADR/RID: II (For reference only, please check.)IMDG: II (For reference only, please check.)IATA: II (For reference only, please check.)

14.5Environmental hazards

ADR/RID: NoIMDG: NoIATA: No

14.6Special precautions for user

no data available

14.7Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
TolueneToluene108-88-3203-625-9
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateJuly 15, 2019
Revision DateJuly 15, 2019

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service

  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road

  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail

  • IMDG: International Maritime Dangerous Goods

  • IATA: International Air Transportation Association

  • TWA: Time Weighted Average

  • STEL: Short term exposure limit

  • LC50: Lethal Concentration 50%

  • LD50: Lethal Dose 50%

  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/


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